Degree of Polymerization | Molecular Weight Calculations | Molecular Weight Definitions
Poiseuille's Law | Mark Houwink Equation
Enthalpy Change of Mixing Entropy Change of Mixing | Gibbs Free Energy of Mixing
Bulk Modulus | Young's Modulus ...
Random Coil |
50mer polymer

dynamic mechanical analysis

Dynamic Mechanical Analysis applies an oscillating force to a polymer and measures displacement. This measures the "stiffness" of the polymer, and the time lag determines the damping of the polymer.

The instrument controls the amplitude and frequency of the oscillating force, and the temperature can also be varied.

In the illustration of a DMA plot below, G' and G", with units of Pascals, are graphed relative to the axis on the left, and tan delta, with no units, is graphed relative to the axis on the right. They are graphed versus increasing temperature. Plots with vs. frequency or strain are also possible.




G', Elastic modulus

G", Viscous modulus

tan d, Damping coefficient

Force- measured using the voltage or current applied to the drive motor
Strain- measured by displacement sensors

A new development (2000)- Force and displacement are measured at the sample clamps.


Other Thermal Analysis Pages: